A novel high-pressure monoclinic metallic phase of V2O3
Y. Ding, C.-C. Chen, Q. Zeng, H.-S. Kim, M. J. Han, M. Balasubramanian, R. Gordon, F. Li, L. Bai, D. Popov, S. M. Heald, T. Gog, H. Mao, and M. van Veenendaal, Phys. Rev. Lett. 112, 056401 (2014); Editor’s Selection.
Vanadium sesquioxide, V2O3, is a prototypical metal-to-insulator system where, in temperaturedependent studies, the transition always coincides with a corundum-to-monoclinic structural transition. As a function of pressure, V2O3 follows the expected behavior of increased metallicity due to a larger bandwidth for pressures up to 12.5 GPa. Surprisingly, for higher pressures when the structure becomes
unstable, the resistance starts to increase. Around 32.5 GPa at 300 K, we observe a novel pressure-induced corundum-to-monoclinic transition between two metallic phases, showing that the structural phase transition can be decoupled from the metal-insulator transition. Using x-ray Raman scattering, we find that screening effects, which are strong in the corundum phase, become weakened at high pressures. Theoretical calculations indicate that this can be related to a decrease in coherent quasiparticle strength, suggesting that the high-pressure phase is likely a critical correlated metal, on the verge of Mott-insulating behavior
Momentum-dependenced in K-edge resonant inelastic X-ray scattering and its application to screening dynamics in CE-phase La0.5Sr1.5LaNiO4
We present a formula for the calculation of K-edge resonant inelastic x-ray scattering on transition-metal compounds, based on a local interaction between the valence shell electrons and the 1s core hole. Extending a previous result, we include explicit momentum dependence and a basis with multiple core-hole sites. We apply
T. F. Seman, X. Liu, J. P. Hill, M. van Veenendaal, and K. H. Ahn, Phys. Rev. B. 90, 045111 (2014).
this formula to a single-layered charge-, orbital-, and spin-ordered manganite, La0.5Sr1.5MnO4, and obtain good agreement with experimental data, in particular with regards to the large variation of the intensity with momentum. We find that the screening in La0.5Sr1.5MnO4 is highly localized around the core-hole site and demonstrate the potential of K-edge resonant inelastic x-ray scattering as a probe of screening dynamics in materials.
Small-angle scattering data analysis in GSAS-II
The General Structure Analysis System II (GSAS-II) now contains modules for the analysis of small-angle X-ray scattering data. This includes processing of two-dimensional images to create corrected one-dimensional patterns, analysis via maximum entropy or total nonnegative least-squares methods of the size distribution, assuming polydispersity, in the dilute limit, and modeling of the one-dimensional data with combinations of Guinier/Porod, Porod, both dilute andcondensedpopulationsofscatteringobjects,andBraggscattering components; slit smearing corrections can be applied where needed. GSAS-II can apply these modeling tools over a sequence of data collected while some experimental condition is varied. This sequential refinement result can then be subjected to a post refinement analysis to determine global parameters encompassing the entire experiment.
R. B. Von Dreele, J. Appl. Crystallography 47, 1784 (2014).